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Tutorial: Lewis Structures for Covalent Compounds


This tutorial assumes that you already know how to draw Lewis symbols for atoms and monatomic ions. Lewis structures, when used with some additional theory, are very useful for predicting the shape of a molecule or a polyatomic ion. Just like any tool, it does have strengths and limitations. This tutorial will show the strengths while also exploring its limitations.

Just a note of clarification. From now on, when this tutorial talks about molecules, it's also referring to polyatomic ions. I simply don't want to type "molecules or polyatomic ions" all the time. Hey, I'm lazy...

We also need to get something very clear at this stage. If you commit the following to memory, it will save you a great deal of trouble in the future. Here it is-

"Lewis structures by themselves say absolutely nothing about the shape of a molecule."

Was that perfectly clear? I hope so! You can use Lewis structures to help determine the shape of a molecule but you need to be introduced to some additional material.

Here are the different sections to this tutorial:

Part 1- Basics:

This section outlines the basic rules for simple molecules (no polyatomic ions), how to determine the total number of valence electrons in the molecule, and how to draw a basic Lewis structure.

Part 2- Multiple Bonds and Polyatomic Ions:

We introduce multiple bonds and how to draw Lewis structures for polyatomic ions.

Part 3- Resonance:

For some molecules, a single structure may not be sufficient. When we can use multiple Lewis structures to describe a molecule, we use resonance structures.

Part 4- Hypervalency:

When we need to exceed the octet rule for the central atom, we use the idea of hypervalency.

Part 5- Formal Charge I:

Calculating formal charges.

Part 6- Formal Charge II:

Formal charges and the "best" Lewis structure.

Part 7- Electron Deficiency:

Electron deficient Lewis structures.

Part 8- Oxoacids:

Oxoacids.

Part 9- Quizzes:

And, because you can never have enough practice, here's a chance to practice everything you've learned.



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