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Lewis Structures' Tutorial

Part 7: Electron Deficiency


Pull up the Periodic Table if you need one.

Here's a current list of the rules.

Let's take a look at BeCl2 and jump in with both feet.

BeCl2

Your turn- enter your answer in the first box and hit "Verify" to see how you did.
1. Total number of valence electrons.
2. Draw the skeleton structure.
BeCl2 skeleton
3. Connect the atoms by making bonds.
BeCl2 bonds
4. Satisfy the octet rule for the surrounding atoms.
BeCl2 Cl octet
5. Satisfy the octet rule for the central atom.
BeCl2 Be octet

Let's take a look at the final structure. Go ahead and calculate the formal charge for all of the atoms.

Your turn- enter your answer for the formal charges and hit "Verify"
Using this Lewis structure: BeCl2
Formal charge for each chlorine.
Formal charge for beryllium.
Sum up the formal charges.

We can do better. The title of this section is a big clue- "electron deficient". Here's the Lewis symbol for beryllium-

beryllium Lewis symbol

Beryllium tends to only make 2 bonds instead of the typical 4 we're used to. So, we skip the last step when we satisfied the octet rule for the central atom. Calculate the formal charges for this structure-

Your turn- enter your answer for the formal charges and hit "Verify"
Using this Lewis structure: BeCl2
Formal charge for each chlorine.
Formal charge for beryllium.
Sum up the formal charges.

To summarize, for beryllium compounds we stop at 2 bonds and we don't complete the octet for the central atom. Boron compounds work similarly. Here's the Lewis symbol for boron-

boron Lewis symbol

Boron compounds tend to have only three bonds to the central boron atom. Let's modify the list of the rules.

Now try BCl3.

BCl3

Your turn- enter your answer for the formal charges and hit "Verify"
1. Total number of valence electrons.
2. Draw the skeleton structure.
BCl3 skeleton
3. Connect the atoms by making bonds.
BCl3 bonds
4. Satisfy the octet rule for the surrounding atoms.
BCl3 Cl octet
5. Satisfy the octet rule for the central atom.
(No need since it's an electron deficient compound)
BCl3 Be octet

Just to make sure, let's take a look at the formal charge for all the atoms.

Your turn- enter your answer for the formal charges and hit "Verify"
Using this Lewis structure: BCl3 Lewis structure
Formal charge for each chlorine.
Formal charge for boron.
Sum up the formal charges.


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